Plate Nº 54 · recorded October 10, 2026
Chemistry & MaterialsReported finding
Plasma Treatment Makes Plant-Based Packaging Nearly Waterproof
A plasma-deposited coating cut liquid water absorption in wood-fiber packaging films to under 1%, NC State researchers report in Applied Surface Science, edging biodegradable wraps closer to plastic.
By Elena Vasquez3 min read659 words
In brief
- A plasma-treated coating reduced liquid water absorption in CNF films to less than 1%.
- The study was published in the journal Applied Surface Science (DOI: 10.1016/j.apsusc.2026.168134).
- Researchers used dielectric barrier discharge (DBD) plasma, a technology already used in the packaging industry.
- A second tested coating weakened the moisture barrier, letting more water vapor pass through — useful for breathable wound dressings.
- DBD plasma is more sustainable than chemical coating, which uses large amounts of water and produces toxic waste.
A plasma-treated coating reduced liquid water absorption in plant-based packaging films to less than 1%, according to a new study published in the journal Applied Surface Science. The finding points to a scalable route for replacing everyday plastic wraps with biodegradable materials made from wood and other plant fibers.
Researchers at North Carolina State University used dielectric barrier discharge (DBD) plasma — an electrically energized gas already common in the packaging industry — to deposit layered protective coatings onto films made from cellulosic nanofibrils (CNF), ultrafine fibers extracted from renewable biomass such as wood pulp.
One coating blocked liquid water almost completely. Another had the opposite effect: it weakened the film's moisture barrier and let more water vapor pass through. That contrast, the researchers say, demonstrates that DBD plasma can precisely tune how CNF films interact with moisture.
"This research provides a practical strategy for turning natural plant and tree fibers into functional, water-resistant packaging. It moves society one step closer to replacing everyday plastic wraps with truly renewable, biodegradable materials," said Nathalie Lavoine, one of the study's lead authors and an associate professor in NC State's Department of Forest Biomaterials.
Why does moisture matter so much?
CNF films tick many boxes for sustainable packaging. They are fully biodegradable and block oxygen and grease effectively. But cellulose naturally attracts water, so the films soak up moisture from their surroundings almost immediately.
That absorption erodes the films' structure. They lose strength, and their gas-barrier performance drops sharply — which in practice means shorter shelf life and weaker product protection.
Consider a potato chip bag. If a CNF-based bag sat in high humidity, moisture could pass through the film and reach the chips, leaving them stale and soft. For some foods, moisture also encourages bacterial growth, raising the risk of foodborne illness.
What is wrong with today's packaging?
Many familiar products — chip bags, candy wrappers, squeeze pouches — combine multiple layers of petroleum-based plastics with materials like aluminum foil or paper. The layers are hard to separate, so standard recycling facilities often cannot process them. Much of this packaging ends up in landfills, where it can break down into microplastics that contaminate soil and water.
CNF films offer a renewable alternative, but their poor moisture performance has kept them out of widespread industrial use. This is the gap the plasma work targets: the treatment modifies the film surface to block water while preserving the cellulose's original mechanical strength and structural integrity.
Is the technology ready for factories?
Lavoine sees two practical advantages over traditional chemical coating processes, which consume large amounts of water, generate high heat and produce toxic waste. Plasma treatment avoids those burdens, making it more sustainable. And because the packaging industry already uses DBD plasma, the treatment could slot into existing manufacturing lines without a major retooling.
The study, led by Mirela A. Artner and colleagues and appearing in Applied Surface Science, applied organosilicon coatings through the DBD plasma process — depositing silicon-based layers directly onto the film surface.
What still needs fixing?
Real-world deployment is not immediate. Lavoine and her collaborators must first refine the process so it does not let water vapor leak through — the very failure seen with one of the tested coatings.
That permeability is not useless. For medical products such as breathable wound dressings, a film that lets vapor through is exactly what designers want. But packaging applications that demand moisture resistance would need the effect minimized.
The team also says further testing and optimization are required to assess:
- coating speeds on production lines,
- energy consumption,
- physical durability during real-world handling,
- economic viability and environmental safety.
Until those questions are answered, the under-1% absorption result remains a laboratory milestone rather than a shelf-ready product. Still, it shows that a dry, scalable, industry-familiar process can give plant fibers a property they lack naturally — and bring biodegradable packaging closer to the supermarket aisle.
via Phys.org Chemistry (Source)
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